2.1mm is more common. So you have a charger and want to know the proper charge port, right? If you have a caliper you could measure the hole. Or you plug the charger into a charge port of any low power device (with this system), if it fits it’s 99% 2.1mm.
Here a pic, on the left side 2.5mm, both on the right side are 2.1mm. The plug on the outer right is low quality.
The poor right one is my 12s 4A charger which I already replaced because the former plug melted away (including plastic port). I still charge with this plug but after seeing my own pic I have to find proper quality 2.1mm x 5.5mm charge plugs.
The best way to avoid problems is to touch charge plug and port once in a while to check temp. If it’s a bit warm it’s ok but if it’s quite warm or hot then there is something wrong.
I also charge with 8A (2.1mm x 5.5mm charge plug and port) and it’s just a bit warm.
You should measure with a multimeter to check which pin goes to which part of the charger; If I recall correctly, then those 2 outer pins were both minus (that, or one was just useless )
Personally I don’t use that type of charge port anymore because the metal one is the same size but supports higher current.